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Graphene consists of a planar structure, with carbon atoms connected in a hexagonal shape that resembles a beehive. When graphene is reduced to several nanometers (nm) in size, it becomes a graphene quantum dot that exhibits fluorescent and semiconductor properties. Graphene quantum dots can be used in various applications as a novel material, including display screens, solar cells, secondary batteries, bioimaging, lighting, photocatalysis, and sensors. Interest in graphene quantum dots is growing, because recent research has demonstrated that controlling the proportion of heteroatoms (such as nitrogen, sulfur, and phosphorous) within the carbon structures of certain materials enhances their optical, electrical, and catalytic properties.

The Korea Institute of Science and Technology (KIST, President Seok-Jin Yoon) reported that the research team led by Dr. Byung-Joon Moon and Dr. Sukang Bae of the Functional Composite Materials Research Center have developed a technique to precisely control the bonding structure of single heteroatoms in the graphene quantum dot, which is a zero-dimensional carbon nanomaterial, through simple chemical reaction control; and that they identified the relevant reaction mechanisms.

With the aim of controlling heteroatom incorporation within the graphene quantum dot, researchers have previously investigated using additives that introduce the heteroatom into the dot after the dot itself has already been synthesized. The dot then had to be purified further, so this method added several steps to the overall fabrication process. Another method that was studied involved the simultaneous use of multiple organic precursors (which are the main ingredients for dot synthesis), along with the additives that contain the heteroatom. However, these methods had significant disadvantages, including reduced crystallinity in the final product and lower overall reaction yield, since several additional purification steps had to be implemented. Furthermore, in order to obtain quantum dots with the chemical compositions desired by manufacturers, various reaction conditions, such as the proportion of additives, would have to be optimized.

The involvement between electron transfer (ET) and catalytic reaction at electrocatalyst surface makes electrochemical process challenging to understand and control. How to experimentally determine ET process occurring at nanoscale is important to understand the overall electrochemical reaction process at active sites.

Recently, a research group led by Prof. LI Can and Prof. FAN Fengtao from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS) captured the electron transfer imaging in electrocatalysis process.

This study was recently published in the journal Nano Letters.

A common strategy to make vaccines more powerful is to deliver them along with an adjuvant — a compound that stimulates the immune system to produce a stronger response.

Researchers from MIT, the La Jolla Institute for Immunology, and other institutions have now designed a new nanoparticle adjuvant that may be more potent than others now in use. Studies in mice showed that it significantly improved antibody production following vaccination against HIV, diphtheria, and influenza.

“We started looking at this particular formulation and found that it was incredibly potent, better than almost anything else we had tried,” says Darrell Irvine, the Underwood-Prescott Professor with appointments in MIT’s departments of Biological Engineering and Materials Science and Engineering; an associate director of MIT’s Koch Institute for Integrative Cancer Research; and a member of the Ragon Institute of MGH, MIT, and Harvard.

A 2D nanomaterial consisting of organic molecules linked to metal atoms in a specific atomic-scale geometry shows non-trivial electronic and magnetic properties due to strong interactions between its electrons.

A new study, published today, shows the emergence of magnetism in a 2D organic material due to strong electron-electron interactions; these interactions are the direct consequence of the material’s unique, star-like atomic-scale structure.

This is the first observation of local magnetic moments emerging from interactions between electrons in an atomically thin 2D organic material.

The extra juice comes from a secret ingredient…corn starch.

Could a simple materials change make electric car batteries able to four times more energy? Scientists in South Korea think so. In a new paper in the American Chemical Society’s Nano Letters, a research team details using silicon and repurposed corn starch to make better anodes for lithium ion batteries.

This team is based primarily in the Korea Institute of Science and Technology (KIST), where they’ve experimented with microemulsifying silicon, carbon, and corn starch into a new microstructured composite material for use as a battery anode. This is done by mixing silicon nanoparticles and corn starch with propylene gas and heating it all to combine.

Continue reading “Corny Lithium-Ion Batteries Could Hold Quadruple the Charge” »

“It is like using your thumb to control the water spray from a hose,” said Ming Liu, associate professor in UC Riverside’s Marlan. “You know how to get the desired spraying pattern by changing the thumb position, and likewise, in the experiment, we read the light pattern to retrieve the details of the object blocking the five nm-sized light nozzles.”

The light is then focused into a spectrometer, where it forms a tiny ring shape. The researchers can formulate the absorption and scattering images with colors by scanning the probe over an area and recording two spectra for each pixel.

The team expects the new nano-imaging technology can be an important tool to help the semiconductor industry make uniform nanomaterials with consistent properties for use in electronic devices. The new full-color nano-imaging technique could also be used to improve understanding of catalysis, quantum optics, and nanoelectronics.

It’s one thing to produce nano-scale materials, but it’s an entirely different thing imaging them.

Nanomaterials have many applications, especially in electronics, but they have one issue: They are so small that they don’t reflect enough light to show fine details, such as colors, even with the aid of the most powerful microscopes.

Now, researchers from UC Riverside may have come up with a solution. They have conceived of an imaging technology that compresses lamp light into a nanometer-sized spot, holding that light at the end of a silver nanowire. This allows it to reveal previously invisible details such as colors.

Continue reading “‘Squeezed’ Light Can Give Nano-Imaging a Much Needed Boost” »

A team of researchers at the University of Groningen has developed a multicomponent nanopore machine that approaches single molecule protein sequencing—it uses a design that allows for unfolding, threading and degrading a desired protein. In their paper published in the journal Nature Chemistry, the group describes their nanopore machine, how it works and how close it comes to allowing single molecule protein sequencing. Yi-Lun Ying with Nanjing University has published a News & Views piece in the same journal issue outlining the purpose of macromolecular machines and the work done by the team with this new effort.

It has been a goal of chemists for many years to create a machine of some type that would allow easy analysis of individual protein molecules, similar to devices that have been created to sequence nucleic acids. Such efforts have been stymied by the high degree of complexity of protein molecules. In this new effort, the researchers have come close to achieving that goal. They have built a tiny (900 kDa) multicomponent nanopore machine that is capable of unfolding a given protein and then presenting it to a protein nanopore (a tiny cavity or pore).

The researchers built the machine by placing a chopper of sorts on top of material borrowed from a bacterium. The material works as a tunnel, directing bits from the chopper through a membrane that was designed to mimic the surface of a cell. The chopper breaks a protein into fragmented bits that are easily exported through the nanopore. As they do so, the fragments impact the flow of charged molecules, which leads to the generation of an electrical signal.

A team of researchers from TU Delft managed to design one of the world’s most precise microchip sensors. The device can function at room temperature—a ‘holy grail’ for quantum technologies and sensing. Combining nanotechnology and machine learning inspired by nature’s spiderwebs, they were able to make a nanomechanical sensor vibrate in extreme isolation from everyday noise. This breakthrough, published in the Advanced Materials Rising Stars Issue, has implications for the study of gravity and dark matter as well as the fields of quantum internet, navigation and sensing.

One of the biggest challenges for studying vibrating objects at the smallest scale, like those used in sensors or quantum hardware, is how to keep ambient thermal noise from interacting with their fragile states. Quantum hardware for example is usually kept at near absolute zero (−273.15°C) temperatures, and refrigerators cost half a million euros apiece. Researchers from TU Delft created a web-shaped microchip sensor that resonates extremely well in isolation from room temperature noise. Among other applications, their discovery will make building quantum devices much more affordable.