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Category: chemistry – Page 88

“The planet has a hot core, and that heat source is changing the chemistry of the gases deeper down, but it’s also driving this strong, convective mixing bubbling up from the interior,” said Zafar Rustamkulov.

Gas giant planets within our solar system and exoplanets outside our solar system are known to possess large amounts of gas and small cores, but what if an exoplanet was found to exhibit opposite characteristics? This is what a study published today in Nature hopes to address as a team of international researchers investigated the physical and atmospheric characteristics of WASP-107 b, which is located just over 200 light-years from Earth and has been found to have unique interior characteristics compared to previously discovered exoplanets. These unique findings hold the potential to challenge our understanding of the formation and evolution of gas giant exoplanets, which continue to demonstrate stark contrasts to planets within our solar system.

For the study, the researchers used NASA’s powerful James Webb Space Telescope (JWST) to observe WASP-107 b, discovering that while its radius is slightly less than Jupiter, its mass is only 10 percent of the largest planet in our solar system. Additionally, WASP-107 b possesses methane levels that are one thousand times less than what astronomers anticipated finding, along with having a core whose mass is 12 times larger than the Earth.

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A recent United Nations report found that the world generated 137 billion pounds of electronic waste in 2022, an 82% increase from 2010. Yet less than a quarter of 2022’s e-waste was recycled. While many things impede a sustainable afterlife for electronics, one is that we don’t have systems at scale to recycle the printed circuit boards (PCBs) found in nearly all electronic devices.

PCBs — which house and interconnect chips, transistors and other components — typically consist of layers of thin glass fiber sheets coated in hard plastic and laminated together with copper. That plastic can’t easily be separated from the glass, so PCBs often pile up in landfills, where their chemicals can seep into the environment. Or they’re burned to extract their electronics’ valuable metals like gold and copper. This burning, often undertaken in developing nations, is wasteful and can be toxic — especially for those doing the work without proper protections.

A team led by researchers at the University of Washington developed a new PCB that performs on par with traditional materials and can be recycled repeatedly with negligible material loss. Researchers used a solvent that transforms a type of vitrimer — a cutting-edge class of sustainable polymers — to a jelly-like substance without damaging it, allowing the solid components to be plucked out for reuse or recycling.

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In good news for future animation figureheads, there might be a new way to revive frozen brains without damaging them. Scientists in China have developed a new chemical concoction that lets brain tissue function again after being frozen.

Freezing is effective at keeping organic material from decomposing, but it still causes damage. As the water inside turns to ice, the crystals tear apart the cells. That’s why frozen meat or fruit goes a bit mushy after it’s defrosted – but a bigger problem is that it also happens with organs or tissues chilled for transplant or research.

For the new study, scientists at Fudan University in China experimented with various chemical compounds to see which ones might work to preserve living brain tissue during freezing. They started by testing out promising chemicals on brain organoids – small, lab-grown lumps of brain tissue that develop into different types of related cells.

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Now, new research reveals yet another engineering feat of this ancient animal’s structure: its ability to filter feed using only the faint ambient currents of the ocean depths, no pumping required.

This discovery of natural ‘“zero energy” control by an international research team co-led by University of Rome Tor Vergata and NYU Tandon School of Engineering could help engineers design more efficient chemical reactors, air purification systems, heat exchangers, hydraulic systems, and aerodynamic surfaces.

In a study published in Physical Review Letters, the team found through extremely high-resolution how the skeletal structure of the Venus flower basket sponge (Euplectella aspergillum) diverts very slow deep sea currents to flow upwards into its central body cavity, so it can feed on plankton and other marine detritus it filters out of the water.

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Blood transfusions save lives. In the US alone, people receive around 10 million units each year. But blood banks are always short in supply—especially when it comes to the “universal donor” type O.

Surprisingly, the gut microbiome may hold a solution for boosting universal blood supplies by chemically converting other blood types into the universal O.

Infusing the wrong blood type—say, type A to type B—triggers deadly immune reactions. Type O blood, however, is compatible with nearly everyone. It’s in especially high demand following hurricanes, earthquakes, wildfires, and other crises because doctors have to rapidly treat as many people as possible.

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Scientists use laser ablation technology to develop a deformable micro-supercapacitor. Professor Jin Kon Kim and Dr. Keon-Woo Kim from the Department of Chemical Engineering at Pohang University of Science and Technology (POSTECH), in collaboration with Dr. Chanwoo Yang and Researcher Seong Ju Park from the Korea Institute of Industrial Technology (KITECH), have achieved a significant breakthrough in developing a small-scale energy storage device capable of stretching, twisting, folding, and wrinkling. Their research has been published in the electronic engineering journal, npj Flexible Electronics.

The advent of wearable technology has brought with it a pressing need for energy storage solutions that can keep pace with the flexibility and stretchability of soft electronic devices.

Micro supercapacitors (MSCs) have emerged as a promising candidate for deformable energy storage, due to high-power density, rapid charging, and long cycle life.

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The first and the best-known metallocene is ‘ferrocene’, which contains a single iron atom. Sandwich complexes are now standard topics in inorganic chemistry textbooks, and the bonding and electronic structure of metallocenes are covered in undergraduate chemistry courses. These sandwich molecules are also significant in industry, where they serve as catalysts and are utilized in the creation of unique metallopolymers.

Nobody knows exactly how many sandwich molecules there are today, but the number is certainly in the thousands. And they all have one thing in common: a single metal atom located between two flat rings of carbon atoms. At least that was what was thought up until 2004, when a research group from the University of Seville made a startling discovery.

The Spanish research team succeeded in synthesizing a sandwich molecule that contained not one but two metal atoms. For a long time, this ‘dimetallocene’ containing two zinc atoms remained the only example of its kind until a group in the UK succeeded last year in synthesizing a very similar molecule that contained two beryllium atoms. But now, Inga Bischoff, a doctoral student in Dr. André Schäfer’s research team at Saarland University, has taken things one big step further. She has managed to synthesize in the laboratory the world’s first ‘heterobimetallic’ sandwich complex – a dimetallocene that contains two different metal atoms.

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If you zoom in on a chemical reaction to the quantum level, you’ll notice that particles behave like waves that can ripple and collide. Scientists have long sought to understand quantum coherence, the ability of particles to maintain phase relationships and exist in multiple states simultaneously; this is akin to all parts of a wave being synchronized. It has been an open question whether quantum coherence can persist through a chemical reaction where bonds dynamically break and form.

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Strongly interacting systems play an important role in quantum physics and quantum chemistry. Stochastic methods such as Monte Carlo simulations are a proven method for investigating such systems. However, these methods reach their limits when so-called sign oscillations occur. This problem has now been solved by an international team of researchers from Germany, Turkey, the USA, China, South Korea and France using the new method of wavefunction matching. As an example, the masses and radii of all nuclei up to mass number 50 were calculated using this method. The results agree with the measurements, the researchers now report in the journal “Nature.”

All matter on Earth consists of tiny particles known as atoms. Each atom contains even smaller particles: protons, neutrons and electrons. Each of these particles follows the rules of quantum mechanics. Quantum mechanics forms the basis of quantum many-body theory, which describes systems with many particles, such as atomic nuclei.

One class of methods used by nuclear physicists to study atomic nuclei is the ab initio approach. It describes complex systems by starting from a description of their elementary components and their interactions. In the case of nuclear physics, the elementary components are protons and neutrons. Some key questions that ab initio calculations can help answer are the binding energies and properties of atomic nuclei and the link between nuclear structure and the underlying interactions between protons and neutrons.

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