Lifeboat Foundation

Titan, the already pretty weird moon of Saturn, just got a little bit weirder. Astronomers have detected cyclopropenylidene (C3H2) in its atmosphere — an extremely rare carbon-based molecule that’s so reactive, it can only exist on Earth in laboratory conditions.

In fact, it’s so rare that it has never before been detected in an atmosphere, in the Solar System or elsewhere. The only other place it can remain stable is the cold void of interstellar space. But it may be a building block for more complex organic molecules that could one day lead to life.

“We think of Titan as a real-life laboratory where we can see similar chemistry to that of ancient Earth when life was taking hold here,” said astrobiologist Melissa Trainer of NASA’s Goddard Space Flight Center, one of the chief scientists set to investigate the moon in the upcoming Dragonfly mission launching in 2027.

First introduced into wide use in the middle of the 20th century, nuclear magnetic resonance (NMR) has since become an indispensable technique for examining materials down to their atoms, revealing molecular structure and other details without interfering with the material itself.

“It’s a broadly used technique in chemical analysis, materials characterization, MRI—situations in which you do a non-invasive analysis, but with atomic and molecular details,” said UC Santa Barbara chemistry professor Songi Han. By placing a sample in a strong magnetic field and then probing it with radio waves scientists can determine from the response from the oscillating nuclei in the material’s atoms the molecular structure of the material.

“However, the problem with NMR has been that because it’s such a low-energy technique, it’s not very sensitive,” Han said. “It’s very detailed, but you don’t get much signal.” As a result, large amounts of sample material may be needed relative to other techniques, and the signals’ general weakness makes NMR less than ideal for studying complex chemical processes.

China faces an additional geopolitical challenge in chip fabrication and assembly. Just a handful of Japanese companies dominate the global market in silicon wafers, photoresists, and essential packaging chemicals. These companies are well-regarded for their high-quality production capabilities and their products are not easily replaceable even by a manufacturing heavyweight such as China. In a changing world where strategic concerns are guiding technology flows, China’s chip ambitions can be foiled not just by the US but also by Japan and Taiwan.

China’s state-backed funds may well spur private investment, even producing a few champions, but are unlikely to result in a self-sufficient Chinese chip industry any time soon.

O,.o.

Physicists from MIPT and Vladimir State University, Russia, have converted light energy into surface waves on graphene with nearly 90% efficiency. They relied on a laser-like energy conversion scheme and collective resonances. The paper was published in Laser & Photonics Reviews.

Manipulating light at the nanoscale is a task crucial for being able to create ultracompact devices for optical energy conversion and storage. To localize light on such a small scale, researchers convert optical radiation into so-called surface plasmon-polaritons. These SPPs are oscillations propagating along the interface between two materials with drastically different refractive indices—specifically, a metal and a dielectric or air. Depending on the materials chosen, the degree of surface wave localization varies. It is the strongest for light localized on a material only one atomic layer thick, because such 2-D materials have high refractive indices.

Continue reading “No losses: Scientists stuff graphene with light” »

Magnets are to be found everywhere in our daily lives, whether in satellites, telephones or on fridge doors. However, they are made up of heavy inorganic materials whose component elements are, in some cases, of limited availability.

Now, researchers from the CNRS, the University of Bordeaux and the ESRF (European Synchrotron Radiation Facility in Grenoble)^[1] have developed a new lightweight molecule-based magnet, produced at low temperatures, and exhibiting unprecedented magnetic properties.

This compound, derived from coordination chemistry^[2], contains chromium, an abundant metal, and inexpensive organic molecules. This is the first molecule-based magnet that exhibits a ‘memory effect’ (i.e. it is capable of maintaining one of its two magnetic states) up to a temperature of 240 °C. This effect is measured by what is known as a coercive field, which is 25 times higher at room temperature for this novel material than for the most efficient of its molecule-based predecessors. This property therefore compares well with that of certain purely inorganic commercial magnets.

Cambridge/Jena (16.11.2020) Linkages between organic and inorganic materials are a common phenomenon in nature, e.g., in the construction of bones and skeletal structures. They often enable combinations of properties that could not be achieved with just one type of material. In technological material development, however, these so-called hybrid materials still represent a major challenge today.

A new class of hybrid glass materials

Researchers from the Universities of Jena (Germany) and Cambridge (GB) have now succeeded in creating a new class of hybrid glass materials that combine organic and inorganic components. To do this, the scientists use special material combinations in which chemical bonds between organometallic and inorganic glasses can be generated. They included materials composed of organometallic networks—so-called metal-organic frameworks (MOFs)—which have recently been experiencing rapidly increasing research interest. This is primarily because their framework structures can be created in a targeted manner, from the length scale of individual molecules up to a few nanometers. This achieves a control of porosity which can be adapted to a large number of applications, both in terms of the size of the pores and their permeability, and in terms of the chemical properties prevailing on the pore surfaces.

Interesting.

The building blocks of life can form even before there are stars or planets, a team of researchers have found in a study.

The new research looked at “dark chemistry”, or the ways that new kinds of materials can form without energetic radiation.

Continue reading “The building blocks of life can form even without stars or planets, scientists say” »

Ira Pastor, ideaXme life sciences ambassador and CEO Bioquark interviews Dr. Michelle Francl the Frank B. Mallory Professor of Chemistry, at Bryn Mawr College, and an adjunct scholar of the Vatican Observatory.

Ira Pastor comments:

Continue reading “Tripping Over the Mysteries of the Universe: Molecules, Particles and People” »

Most materials used for optical lighting applications need to produce a uniform illumination and require high mechanical and hydrophobic properties. However, they are rarely eco-friendly. Herein, a bio-based, polymer matrix-free, luminescent, and hydrophobic film with excellent mechanical properties for optical lighting purposes is demonstrated. A template is prepared by turning a wood veneer into porous scaffold from which most of the lignin and half of the hemicelluloses are removed. The infiltration of quantum dots (CdSe/ZnS) into the porous template prior to densification resulted in almost uniform luminescence (isotropic light scattering) and could be extended to various quantum dot particles, generating different light colors. In a subsequent step, the luminescent wood film is coated with hexadecyltrimethoxysilane (HDTMS) via chemical vapor deposition. The presence of the quantum dots coupled with the HDTMS coating renders the film hydrophobic (water contact angle ≈ 140°). This top-down process strongly eliminates lumen cavities and preserves the orientation of the original cellulose fibrils to create luminescent and polymer matrix-free films with high modulus and strength in the direction of fibers. The proposed optical lighting material could be attractive for interior designs (e.g., lamps and laminated cover panels), photonics, and laser devices.