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Archive for the ‘chemistry’ category: Page 2

Sep 4, 2024

Real-time control over a chemical reaction network by light

Posted by in categories: chemistry, energy

Self-assembled molecules are responsible for important cellular processes. Self-assembled structures such as microtubules or actin filaments are key to cell motility: change of shape, division or extension of membranes. These self-assembled entities have the peculiarity of being formed temporarily, since they require energy consumption. Inspired by nature, there is currently an active area of research that attempts to replicate this process of self-assembly artificially, using the so-called chemical reaction networks.

The control of self-assembly by means of chemical reaction networks is based on the activation of a monomer prone to self-assembly, which is then deactivated. In this way, the self-assembled structure requires a continuous energy consumption to perpetuate itself. From a chemical point of view, this energy is provided by a “fuel”, a chemical reagent. Depending on the availability of that energy source, the self-assembly process occurs or not.

Traditionally, highly reactive fuels have been used to carry out the activation, with little control over the deactivation process. This also implies that the activation and deactivation fuels tend to react with each other, making artificial dissipative self-assembly processes ineffective. In nature, these two processes are controlled by catalysts, which increases their efficiency. Thus, the introduction of catalysts in these processes and the control of their activity by external stimuli such as light are highly desirable, since they can limit part of these problems.

Sep 4, 2024

A new method captures the stochastic dynamics in coherent X-ray imaging

Posted by in categories: biological, chemistry, nanotechnology, space

Coherent X-ray imaging has emerged as a powerful tool for studying both nanoscale structures and dynamics in condensed matter and biological systems. The nanometric resolution together with chemical sensitivity and spectral information render X-ray imaging a powerful tool to understand processes such as catalysis, light harvesting or mechanics.

Unfortunately these processes might be random or stochastic in nature. In order to obtain freeze-frame images to study stochastic dynamics, the X-ray fluxes must be very high, potentially heating or even destroying the samples.

Also, detectors acquisition rates are insufficient to capture the fast nanoscale processes. Stroboscopic techniques allow imaging ultrafast repeated processes. But only mean dynamics can be extracted, ruling out measurement of stochastic processes, where the system evolves through a different path in phase space during each measurement. These two obstacles prevent coherent imaging from being applied to complex systems.

Sep 4, 2024

New Quantum Effect in Textbook Chemistry Law

Posted by in categories: chemistry, computing, encryption, law, quantum physics

The observation of quantum modifications to a well-known chemical law could lead to performance improvements for quantum information storage.

The Arrhenius law says that the rate of a chemical reaction should decrease steadily as you increase the energy barrier between initial and final states. Now researchers have found a system that obeys a quantum version of the Arrhenius law, where the rate does not drop smoothly but instead decreases in a staircase pattern [1]. The system is a type of quantum bit (qubit) that is particularly robust against environmental disturbances. The researchers demonstrated that they can take advantage of this quantum effect to improve the qubit’s performance.

Technologies such as quantum computers and quantum cryptography use qubits to store information, and one of the continuing challenges is that uncontrolled environmental effects can change the state of a qubit. The most common solutions require large amounts of hardware, but an alternative method is to use qubits that are more error resistant, such as so-called cat qubits. The information in these qubits is stored in robust combinations of quantum states that resemble the states in Schrödinger’s famous feline thought experiment (see Synopsis: Quantum-ness Put on the Scale).

Sep 4, 2024

Assorted, distinctive behavior of molten uranium salt revealed by neutrons

Posted by in categories: chemistry, nuclear energy

In a paper published in the Journal of the American Chemical Society, researchers have documented for the first time the unique chemistry dynamics and structure of high-temperature liquid uranium trichloride (UCl3) salt, a potential nuclear fuel source for next-generation reactors.

Sep 3, 2024

Chemists find new pharmaceutically active substances from billions of newly combined molecules

Posted by in categories: biotech/medical, chemistry

Nowadays, there’s lots of buzz about spectacular new medical treatments, such as personalized cancer therapy with modified immune cells or antibodies. Such treatments, however, are very complex and expensive and so find only limited application. Most medical therapies are still based on small chemical compounds that can be produced in large quantities and thus at low cost.

Sep 3, 2024

Quantum-dot-enabled infrared hyperspectral imaging with single-pixel detection

Posted by in categories: chemistry, food, information science, military, quantum physics

Widely utilized across various industries such as chemistry, agriculture, and military, this technology relies on strategies like dispersive optics and narrow-band light filters.

However, limitations exist in these approaches. Additionally, the fabrication of large-scale InGaAs detector arrays poses challenges, necessitating the development of new experimental methods and algorithms to advance infrared hyperspectral imaging technology in terms of miniaturization and cost-effectiveness.

In a paper published in Light Science & Applications, a team led by Professor Baoqing Sun and Yuan Gao from Shandong University introduce a novel method for encoding near-infrared spectral and spatial data.

Sep 2, 2024

Near‐Infrared Light Activated Formulation for the Spatially Controlled Release of CRISPR‐Cas9 Ribonucleoprotein for Brain Gene Editing

Posted by in categories: bioengineering, biotech/medical, chemistry, nanotechnology, neuroscience

A nanoparticle formulation, using oligonucleotide chemistry, able to release a gene editing system with single cell resolution after near infrared laser activation. The full potential of the formulation was demonstrated in the brain after intracerebral and intranasal administrations. The spot of the laser defined the region of gene editing.

Sep 2, 2024

On the way to optical logic gates: Study demonstrates the basics for purely optical processing of information

Posted by in categories: chemistry, physics

In a collaboration between scientists from Physics and Chemistry at the University of Bayreuth and Physical Chemistry at the University of Melbourne, it has now been possible to realize optically switchable photonic units that enable precise addressing of individual units. This will make it possible to reliably store and read binary information optically.

Sep 1, 2024

Scientists make breakthrough discovery with the power to permanently change plastic pollution: ‘Transforming … pollutants into valuable, reusable chemicals’

Posted by in categories: chemistry, computing, sustainability

Scientists at the University of Texas used a breakthrough laser recycling technique to turn plastic into computer components.

Sep 1, 2024

Mitochondria Dump DNA in The Brain, Potentially Cutting Years Off Our Lives

Posted by in categories: biotech/medical, chemistry, neuroscience, nuclear energy

Scraps of DNA discarded by our neurons’ power units are being absorbed into our nuclear genome far more frequently than assumed, potentially putting our brains at greater risk of developing life-threatening conditions.

An investigation by a team of researchers led by Columbia University in the US has found individuals with higher numbers of nuclear mitochondrial insertions – or NUMTs (pronounced new-mites) – in their brain cells are more likely to die earlier than those with fewer DNA transfers.

Continue reading “Mitochondria Dump DNA in The Brain, Potentially Cutting Years Off Our Lives” »

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