Lifeboat Foundation

A team of researchers from Lawrence Livermore National Laboratory (LLNL) and the University of Michigan has found that the rate of cooling in reactions dramatically affects the type of uranium molecules that form.

The team’s experimental work, conducted over about a year and a half starting in October 2020, attempts to help understand what uranium compounds might form in the environment after a nuclear event. It has recently been detailed in Scientific Reports.

“One of our most important findings was learning that the rate of cooling affects the behavior of uranium,” said Mark Burton, the paper’s lead author and a chemist in the Lab’s Materials Science Division. “The big picture here is that we want to understand uranium chemistry in energetic environments.”

An apparent scooping turned into something much more valuable.

Before starting their weekend, Rosie Somerville and Marina Pérez-Jiménez decided to quickly check the latest literature. A few minutes later, the lab WhatsApp group was on fire. After months of arduous work on different organometallic complexes, some of them had just been published. What now?

Very often, researchers across the world work on similar developments without knowing about each other’s results. The latest recipients of the Nobel prize for chemistry, Benjamin List and Dave MacMillan, independently developed organocatalysis. But sometimes the science hall of fame works on a first-come, first-served basis. What if someone scoops the discovery?

The Dubai facility has the capacity to produce over two million pounds of leafy greens annually, and will grow lettuces, arugula, mixed salad greens, and spinach.

ECO stands for Emirates Crop One; the vertical farm is a joint venture between Crop One Holdings (a Massachusetts-based vertical farming company) and Emirates Flight Catering (the catering business that serves Emirates Airlines). Greens from the vertical farm will be served onboard Emirates flights, and will also be sold in grocery stores in the UAE. Since they’re grown in a sterile environment without pesticides, herbicides, or chemicals, the greens come ready-to-eat and don’t need to be washed.

The UAE is in many ways an ideal location for vertical farming, if not a place where the technology may soon become essential. It gets an abundance of sunlight but doesn’t have much water to speak of (it was, fittingly, the field testing site for a nanoparticle technology that helps sandy soil retain water and nutrients); that means vertical farms could use energy from solar panels to grow food indoors using 95 percent less water than traditional agriculture.

Circa 2013

The extremely heavy element was just confirmed by scientists in Sweden. We talk to a chemist about the discovery—and what it means.

Stir this silicon-based powder into water, and hydrogen will bubble out, ready for immediate use. Hong Kong company EPRO Advance Technology (EAT) says its Si+ powder offers an instant end to the difficulties of shipping and storing green energy.

This is the second powdered hydrogen advance we’ve learned about this week, designed to solve the same problems: transporting hydrogen is difficult, dangerous and expensive, whether the costs are for cryogenic cooling in a liquid hydrogen system, or for compression to around 700 times the normal sea-level air pressure.

Continue reading “Another hydrogen transport powder emerges, promising double the density” »

In what’s being hailed as an important first for chemistry, an international team of scientists has developed a new technology that can selectively rearrange atomic bonds within a single molecule. The breakthrough allows for an unprecedented level of control over chemical bonds within these structures, and could open up some exciting possibilities in what’s known as molecular machinery.

Molecules are made up of clusters of atoms, and are the product of the nature and arrangement of those atoms within. Where oxygen molecules we breathe feature the same repeating type of atom, sugar molecules are made of carbon, oxygen and hydrogen.

Scientists have been pursuing something called “selective chemistry” for some time, with the objective of forming exactly the type of chemical bonds between atoms that they want. Doing so could lead to the creation of complex molecules and devices that can be designed for specific tasks.

Microplastics, tiny particles of plastic that are now found worldwide in the air, water, and soil, are increasingly recognized as a serious pollution threat, and have been found in the bloodstream of animals and people around the world.

Some of these microplastics are intentionally added to a variety of products, including agricultural chemicals, paints, cosmetics, and detergents—amounting to an estimated 50,000 tons a year in the European Union alone, according to the European Chemicals Agency. The EU has already declared that these added, nonbiodegradable microplastics must be eliminated by 2025, so the search is on for suitable replacements, which do not currently exist.

Now, a team of scientists at MIT and elsewhere has developed a system based on silk that could provide an inexpensive and easily manufactured substitute. The new process is described in a paper in the journal Small, written by MIT postdoc Muchun Liu, MIT professor of civil and environmental engineering Benedetto Marelli, and five others at the chemical company BASF in Germany and the U.S.

Proteins serve a variety of purposes in plants in addition to being the fundamental building blocks of life. More than 20 billion protein molecules make up a typical plant cell, helping to stabilize its structure and sustain cellular metabolism.

Researchers at Heidelberg University’s Centre for Organismal Studies have shed light on a biological process that increases the life of plant proteins. They have now discovered a crucial protein, called N-terminal acetylation, that controls this mechanism. The study’s findings were published in the journals Molecular Plant and Science Advances.

N-terminal acetylation is a chemical marker that develops during the production of proteins. Plants do this by affixing an acetic acid.

New electrocatalysis electrodes have been created that are simpler and cheaper than conventional ones, and can substantially increase the efficiency of water splitting. Decorated with chiral molecules like helicenes, these devices double the activity of the oxygen evolution reaction, the bottleneck of the process, and improve its selectivity.

‘With electrocatalysis, we [can] use electrons from renewable sources [like solar and wind] to produce clean chemicals and fuels,’ explains Magalí Lingenfelder from the Max Planck–EPFL laboratory for molecular nanoscience and technology, in Switzerland, who led the study. In this work, her team focused on the oxygen evolution reaction. ‘It’s the bottleneck of water splitting,’ she says. ‘We wanted to increase its performance with cheap, simple solutions.’