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Category: chemistry – Page 11

Advancements in (Ca, Ba)ZrS₃ solar cells using innovative spinel hole transport layers

Solar power has long been a beacon of hope in our pursuit of clean energy. However, the road to sustainable, high-efficiency photovoltaics has been riddled with roadblocks such as toxicity and instability in widely used lead halide perovskites. Could we engineer a solar cell that delivers not just high performance, but also durability, stability and environmental safety?

That question led us to (Ca, Ba)ZrS3, a chalcogenide perovskite with immense promise. Unlike its lead-based counterparts, this material boasts strong thermal and chemical stability. More importantly, its bandgap can be finely tuned down to 1.26 eV with less than 2% calcium doping, placing it squarely within the Shockley-Queisser limit for optimal photovoltaic conversion.

For the first time, my research team at the Autonomous University of Querétaro explored an innovative idea of pairing (Ca, Ba)ZrS3 with next-generation inorganic spinel hole transport layers (HTLs). We integrated NiCo2O4, ZnCo2O4, CuCo2O4, and SrFe2O4 into solar cells and simulated their performance using SCAPS-1D.

Targeting malaria at the source: Drug-treated nets eliminate parasites in resistant mosquitoes

Researchers have identified a type of chemical compound that, when applied to insecticide-treated bed nets, appears to kill the malaria-causing parasite in mosquitoes.

Published in the journal Nature, the multi-site collaborative study represents a breakthrough for a disease that continues to claim more than half a million lives worldwide every year. A lab at Oregon Health & Science University played a key role, and the National Institute of Allergy and Infectious Diseases, of the National Institutes of Health, supported the research.

Michael Riscoe, Ph.D., professor of molecular microbiology and immunology in the OHSU School of Medicine, designed and synthesized the anti-malarial drugs, termed ELQs, that were then screened in the lab of Flaminia Catteruccia, Ph.D., the study’s senior author and Irene Heinz Given Professor of Immunology and Infectious Diseases at the Harvard T.H. Chan School of Public Health.

Scientists identify new 2D copper boride material with unique atomic structure

More than ten years ago, researchers at Rice University led by materials scientist Boris Yakobson predicted that boron atoms would cling too tightly to copper to form borophene, a flexible, metallic two-dimensional material with potential across electronics, energy and catalysis. Now, new research shows that prediction holds up, but not in the way anyone expected.

Unlike systems such as graphene on , where atoms may diffuse into the substrate without forming a distinct alloy, the in this case formed a defined 2D copper boride ⎯ a new compound with a distinct atomic structure. The finding, published in Science Advances by researchers from Rice and Northwestern University, sets the stage for further exploration of a relatively untapped class of 2D materials.

“Borophene is still a material at the brink of existence, and that makes any new fact about it important by pushing the envelope of our knowledge in materials, physics and electronics,” said Yakobson, Rice’s Karl F. Hasselmann Professor of Engineering and professor of materials science and nanoengineering and chemistry. “Our very first theoretical analysis warned that on copper, boron would bond too strongly. Now, more than a decade later, it turns out we were right ⎯ and the result is not , but something else entirely.”

Unique chemistry discovered in critical lithium deposits

Much of the world’s lithium occurs in salty waters with fundamentally different chemistry than other naturally saline waters like the ocean, according to a study published on May 23 in Science Advances. The finding has implications for lithium mining technologies and wastewater assessment and management.

Lithium is a critical mineral in the renewable energy sector. About 40% of global lithium production comes from large pans, called salars, in the central Andes Mountains in South America and the Tibetan Plateau in Asia. In these arid, high-altitude regions, lithium exists below surface salt deposits, dissolved in extremely saline water called .

“We discovered that the pH of brines in these regions is almost entirely driven by boron, unlike seawater and other common saline waters. This is a totally different geochemical landscape, like studying an extraterrestrial planet,” said Avner Vengosh, distinguished professor of environmental quality and Chair of the Division of Earth and Climate Sciences at Duke University’s Nicholas School of the Environment, who oversaw the research.

Moving pictures: Researchers use movies to diagnose EV battery failure

Charging electric-vehicle batteries in Ithaca’s frigid winter can be tough, and freezing temperatures also decrease the driving range. Hot weather can be just as challenging, leading to decomposition of battery materials and, possibly, catastrophic failure.

For (EVs) to be widely accepted, safe and fast-charging lithium-ion batteries need to be able to operate in extreme temperatures. But to achieve this, scientists need to understand how materials used in EVs change during temperature-related chemical reactions, a so-far elusive goal.

Now, Cornell chemists led by Yao Yang, Ph.D. ‘21, assistant professor of chemistry and chemical biology in the College of Arts and Sciences, have developed a way to diagnose the mechanisms behind battery failure in extreme climates using electron microscopy. Their first-of-its-kind operando (“operating”) electrochemical transmission electron microscopy (TEM) enables them to watch chemistry in action and collect real-time movies showing what happens to energy materials during temperature changes.

Unlocking Scalable Chemistry Simulations for Quantum-Supercomputing

We’re announcing the world’s first scalable, error-corrected, end-to-end computational chemistry workflow. With this, we are entering the future of computational chemistry.

Quantum computers are uniquely equipped to perform the complex computations that describe chemical reactions – computations that are so complex they are impossible even with the world’s most powerful supercomputers.

However, realizing this potential is a herculean task: one must first build a large-scale, universal, fully fault-tolerant quantum computer – something nobody in our industry has done yet. We are the farthest along that path, as our roadmap, and our robust body of research, proves. At the moment, we have the world’s most powerful quantum processors, and are moving quickly towards universal fault tolerance. Our commitment to building the best quantum computers is proven again and again in our world-leading results.

Radiotrophic fungus

Scientists discover fungus species in Chernobyl nuclear zone have mutated to feed on radiation:

Cryptococcus neoformans, discovered at the site in 1991, feeds on radiation through a process called radiosynthesis. Its high levels of melanin absorb harmful radiation and convert it into chemical energy, much like how plants use photosynthesis to create energy.

NASA scientists, in collaboration with Johns Hopkins University, are now testing melanin extracted from the fungi aboard the International Space Station. ’ If successful, this natural shield could protect astronauts and equipment from cosmic rays, a significant challenge for long-term space exploration. “Space radiation is dangerous and damages matter,” explains researcher Radamés J.B. Cordero. “A material like this could shield astronauts and benefit people here on Earth.” This discovery turns a remnant of a nuclear disaster into a potential lifesaver for humanity’s journey into the cosmos.

Learn more.

Radiotrophic fungi are fungi that can perform the hypothetical biological process called radiosynthesis, which means using ionizing radiation as an energy source to drive metabolism. It has been claimed that radiotrophic fungi have been found in extreme environments such as in the Chernobyl Nuclear Power Plant.

Most radiotrophic fungi use melanin in some capacity to survive. [ 1 ] The process of using radiation and melanin for energy has been termed radiosynthesis, and is thought to be analogous to anaerobic respiration. [ 2 ] However, it is not known if multi-step processes such as photosynthesis or chemosynthesis are used in radiosynthesis or even if radiosynthesis exists in living organisms.

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An accidentally discovered class of nanostructured materials can passively harvest water from air

A serendipitous observation in a Chemical Engineering lab at Penn Engineering has led to a surprising discovery: a new class of nanostructured materials that can pull water from the air, collect it in pores and release it onto surfaces without the need for any external energy.

The research, published in Science Advances, describes a material that could open the door to new ways to collect water from the air in arid regions and devices that cool electronics or buildings using the power of evaporation.

The interdisciplinary team includes Daeyeon Lee, Russell Pearce and Elizabeth Crimian Heuer Professor in Chemical and Biomolecular Engineering (CBE); Amish Patel, Professor in CBE; Baekmin Kim, a postdoctoral scholar in Lee’s lab and first author; and Stefan Guldin, Professor in Complex Soft Matter at the Technical University of Munich.